Medium and Message: Soot and milk
Since ancient times people have written, drawn and painted using pigments and dyes in water, often without any binder to adhere them to the ground. These are generically termed inks, and distinct from other media such as watercolours or the temperas. Most common among them is India ink, whose essential ingredients are carbon particles from soot, suspended in water. When applied to a suitably absorbent ground that has stood the test of centuries.

Hieronymus Bosch’s study of The Owl’s Nest from around 1505-1516 is a good example of a pen and ink drawing starting to transcend into painting.

Washes applied using a brush became common in sketches made in front of the motif, such as Egbert van der Poel’s Fire in the Nieuwe Kerk, Amsterdam, in 1645. Known for his paintings of fires, he used these sketches to paint his famous brandjes in the studio. Landscape artists such as Nicolas Poussin and Claude Lorrain used the same sketching media working en plein air to build image libraries for the idealised landscapes used in their finished paintings.

By the early nineteenth century, artists like Samuel Palmer were creating works that are to all intents and purposes full-blown paintings using black and coloured inks, such as this atmospheric nocturne of Cornfield and Church by Moonlight from about 1830.

Used without a binder, inks normally rewet and smudge or blur, so have to be applied after any watercolour. Adding a binder such as shellac to India ink makes it waterproof when it has dried, and this was used in combination with watercolours by illustrators and painters such as the great Arthur Rackham, here in one of his illustrations for an edition of Charles Dickens’ A Christmas Carol.
A related medium that also crossed over from drawings and illustrations into paintings is casein, a protein-based tempera. It too has a long history, but didn’t become popular among artists until the late nineteenth century. Casein is a protein originally obtained from sour milk, but by the nineteenth century it was more usually prepared by the addition of rennet, enzymes used in cheese manufacture, extracted from the stomachs of calves.
Casein powder is then turned into paint by dispersion in an alkaline solution, typically made from lime or borax, and pigment is ground in. When lime is used the paint works best on porous grounds, but must be used fresh. When a little linseed oil is added to borax casein, a shelf-life of several months or more is possible. Casein paints dry as quickly as egg tempera, but can be reworked for a period until their binder has fully hardened. Once that has taken place, their paint film is robust and stable.

The earliest painting I have seen that is known to have been made using casein paints is William Morris Hunt’s unusual view of Niagara from 1879. Hunt deviated here from his customary use of oils, although he still applied his paint to a prepared canvas support.

One of the most famous artists to have used casein paint is Gustav Klimt. In 1902, he used it in a frieze of 24 metres (nearly 80 feet) length for the fourteenth exhibition of the Vienna Secession, his Beethoven Frieze, of which that above is a section known as The Hostile Powers, and that below is Nagging Grief. He applied his casein paint directly onto mortar with added stucco, gold leaf, and other materials. This is known to be a robust form of wall-painting that is much more accommodating than fresco, and just as enduring, but has never become popular.


A few of Colin Campbell Cooper’s skyscraper cityscapes were painted using casein media, including this view of Flatiron Building, Manhattan from about 1908. He was equally proficient in watercolour and oils, and I don’t know why he experimented with casein, nor why he used it so infrequently.

Another Vienna-based artist, Albin Egger-Lienz, also used casein on occasion, here in this fourth of several different versions of Totentanz (Dance of Death) from 1915.
During the twentieth century, casein paints didn’t become popular but continued in use, particularly by those who also made illustrations. Just when they were attracting a following among artists such as Andy Warhol, they were rapidly displaced by acrylics. Despite that, casein paint is still available today, sold by Pelikan under the brand name of Plaka.

