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Medium and Message: Surface texture

By: hoakley
14 October 2025 at 19:30

We’re remarkably good at perceiving different surface textures, but find it harder to imagine them in two-dimensional images. While the overwhelming majority of paintings, at least until the twentieth century, consist of a paint layer on a flat ground, there’s nothing that requires the surface of the paint layer to be flat and smooth. But if all you look at are images of paintings, you generally won’t see their surface texture, where the artist has applied and shaped paint in thick layers of impasto, or incised into some of the layer in sgraffito. This article looks in detail at four examples where surface texture in the paint layer is important.

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Arnold Böcklin (1827–1901), Sirens (1875), tempera on canvas, 46 × 31 cm, Alte Nationalgalerie, Berlin. Wikimedia Commons.

Arnold Böcklin’s unusual painting of Sirens from 1875 was made in tempera on canvas, with the ground and paint layers thin enough to let the texture of the canvas weave show through. This image was fortuitously taken with lighting that allows the texture to show.

Another famous tempera painting wasn’t painted on a textured ground, but is one of the earlier paintings to feature impasto as a technique.

Anonymous, The Wilton Diptych (c 1395-9), egg tempera on panel, each panel 53 x 37 cm, The National Gallery, London. Wikimedia Commons.
Artist not known, The Wilton Diptych (c 1395-9), egg tempera on panel, each panel 53 x 37 cm, The National Gallery, London. Wikimedia Commons.

The Wilton Diptych was painted on two small panels of oak wood in the final years of the fourteenth century. That wood was first assembled into the panels, then carved down from a thickness of about 2.5 cm (1 inch) to form an integral frame with a recessed painting surface. A smooth gesso ground was then laid on the wood before the gilded areas were laid onto it using thin sheets of gold leaf, and patterned using a range of punches.

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Artist not known, The Wilton Diptych (detail) (c 1395-9), egg tempera on panel, each panel 53 x 37 cm, The National Gallery, London. Image by Sailko, via Wikimedia Commons.

Details of jewels and similar objects such as the white hart brooches were raised using thicker areas of lead white paint, to give the impression of enamelling. Coupled with mordant gilding, they mimic the three-dimensional form of jewels and act as point reflectors of light, sparkling as if they really were gems in the paint layer, as shown in the details above and below.

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Artist not known, The Wilton Diptych (detail) (c 1395-9), egg tempera on panel, each panel 53 x 37 cm, The National Gallery, London. Image by Sailko, via Wikimedia Commons.

The finest strokes of paint seen here are less than 0.5 mm (1/50th of an inch) across.

From those early days of modern painting until the decline of ‘academic’ painting in the late nineteenth century, patrons, Salon juries and critics expected paint surfaces to be smooth and flat. But there were rebels.

Many of Rembrandt’s paintings from before 1650 have fairly conventional ‘finished’ surfaces, his monumental Night Watch being a good example. By about 1660, though, many of his paintings had quite rough surfaces that significantly alter their optical properties.

Rembrandt Harmenszoon van Rijn, The Jewish Bride (c 1667), oil on canvas, 121.5 x 166.5 cm, Rijksmuseum, Amsterdam. Wikimedia Commons.
Rembrandt Harmenszoon van Rijn (1606–1669), The Jewish Bride (c 1667), oil on canvas, 121.5 x 166.5 cm, Rijksmuseum, Amsterdam. Wikimedia Commons.

One of the best examples of Rembrandt’s use of texture in the paint layer is The Jewish Bride from about 1667, just a couple of years before his death. This is among his works studied by the Rembrandt Research Project.

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Rembrandt Harmenszoon van Rijn (1606–1669), The Jewish Bride (detail) (c 1667), oil on canvas, 121.5 x 166.5 cm, Rijksmuseum Amsterdam. Wikimedia Commons.

In this detail, highlights on the sleeve and jewellery have been applied roughly, although it’s still a matter for speculation as to exactly how he achieved that. Lower down, on the red dress of the bride, the duller top layer of paint has been scraped through to reveal lighter lower layers. The end result is a painting that creates its visual effects as much by its surface textures, as by form or colour.

One of Rembrandt’s secrets that have been sought by so many since lies in how he was able to exploit surface texture in his paint. That is the ‘secret recipe’ which Maroger, Redelius, and others claimed to have discovered. Systematic analyses of Rembrandt’s paint layers by White at the National Gallery in London and the Research Project soundly rebutted the ‘secrets’ claimed. In the main, Rembrandt used linseed oil as his binder, occasionally using walnut oil as well, and just once poppy seed oil.

In some passages the oil had been thickened by heat treatment, but this was by no means widespread. Traces of pine resin found in some samples may have been introduced during retouching, and don’t appear to be a feature of Rembrandt’s impasto work; neither is there any evidence that he added wax to his oil paint to give it body, as some had asserted.

As you might expect, JMW Turner was another such rebel.

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Joseph Mallord William Turner (1775–1851), Seapiece with Fishing Boats off a Wooden Pier, a Gale Coming In (date not known, possibly c 1801), oil on panel, 31.8 x 44.5 cm, Private collection. Wikimedia Commons.

For example, in his Seapiece with Fishing Boats off a Wooden Pier, a Gale Coming In, possibly from as early as 1801, Turner made extensive use of sgraffito, made using a knife, brush handle, or even his fingernails for all we know.

Later that century, Vincent van Gogh developed a more radical approach, in his initial version of Wheat Field with Cypresses from 1889, the year before his death.

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Vincent van Gogh (1853–1890), Wheat Field with Cypresses (1889), oil on canvas, 73.2 × 93.4 cm, Metropolitan Museum of Art, New York, NY. Wikimedia Commons.

It’s possible that he completed this painting in a single sitting, as this seems to have been intended as an oil sketch for a more finished version which he painted later that summer.

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Vincent van Gogh (1853–1890), Wheat Field with Cypresses (detail) (1889), oil on canvas, 73.2 × 93.4 cm, Metropolitan Museum of Art, New York, NY. Wikimedia Commons.

The detail above shows the tops of the wheat towards the lower left of the field, in the foreground. Over his initial thin layers of paint, van Gogh laid thick gestural strokes of highly chromatic paint, orientating those strokes according to the object they show. In the golden yellow of the wheat there are blues and greens, mostly showing through from his underpainting, with superimposed impasto of pale straw, ochre, and pale greens.

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Vincent van Gogh (1853–1890), Wheat Field with Cypresses (detail) (1889), oil on canvas, 73.2 × 93.4 cm, Metropolitan Museum of Art, New York, NY. Wikimedia Commons.

This detail, taken from the edge of the wheatfield at the lower right corner of the painting, shows three distinct areas of brushwork: the diagonal strokes forming the standing wheat, swirling loops to form the grasses and weeds below, and shorter marks forming a more random pattern for the heads of the wheat in the upper section.

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Vincent van Gogh (1853–1890), Wheat Field with Cypresses (detail) (1889), oil on canvas, 73.2 × 93.4 cm, Metropolitan Museum of Art, New York, NY. Wikimedia Commons.

At the centre of the canvas, from where this detail is taken, impasto blue and white have mixed with the green and yellow of the fields below. This shows that much of the painting was painted wet on wet, either in the same session or on consecutive days. Some of the darker green at the right may have been painted later, onto paint that had by then become touch dry.

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Vincent van Gogh (1853–1890), Wheat Field with Cypresses (X-ray) (1889), oil on canvas, 73.2 × 93.4 cm, Metropolitan Museum of Art, New York, NY. Wikimedia Commons.

An X-ray image of the whole painting shows in white those passages likely to contain the most lead white, and some other pigments which are most radio-opaque. This also reveals the pattern of brushstrokes well.

With the introduction of acrylic paints in the latter half of the twentieth century, painters have been able to apply even heavier impasto, and some have used this to paint what are in effect reliefs.

This is why so many paintings have to be seen in the flesh, up close, and in the right light for their full appreciation.

Paintings of windmills after 1850

By: hoakley
31 August 2025 at 19:30

In the first article of this pair looking at paintings of windmills, I covered traditional views up to the first of the pre-Impressionists. This article takes this account from around 1850 up to the period between the two World Wars. Although the development of steam power during the nineteenth century brought great changes to many industries, windmills continued to flourish until the middle of the century, and even then they only declined gradually until the Second World War.

Samuel Palmer, Summer Storm near Pulborough, Sussex (c 1851), watercolour on paper, 51.5 x 72 cm, Art Gallery of South Australia, Adelaide. Wikimedia Commons.
Samuel Palmer, Summer Storm near Pulborough, Sussex (c 1851), watercolour on paper, 51.5 x 72 cm, Art Gallery of South Australia, Adelaide. Wikimedia Commons.

Samuel Palmer’s Summer Storm near Pulborough, Sussex from about 1851 refers to Dutch landscape painting, in a very Kentish context. A storm is seen approaching the rolling countryside near Pulborough, now in West Sussex. On the left, in the middle distance, a small bridge leads across to a hamlet set around a prominent windmill, whose blades are blurred as they are being driven by the rising wind.

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Jean-Léon Gérôme (1824–1904), Recreation in a Russian Camp, Remembering Moldavia (1855), oil on canvas, 59.5 x 101.5 cm, Private collection. The Athenaeum.

Windmill styles differ outside northern Europe. When Jean-Léon Gérôme travelled down the River Danube in about 1855, he claimed to have witnessed this moving scene of Recreation in a Russian Camp, Remembering Moldavia (1855). A group of Russian soldiers in low spirits is being uplifted by making music, under the direction of their superior. Gérôme has captured an atmosphere which few of his other paintings achieved: the marvellous light of the sky, the skein of geese on the wing, and the parade of windmills in the distance, all draw together with the soldiers in their sombre greatcoats.

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Johan Christian Dahl (1788–1857), Burning Windmill at Stege (1856), oil on canvas mounted on cardboard, 68 × 90 cm, Nasjonalgalleriet, Oslo, Norway. Wikimedia Commons.

The following year, JC Dahl’s Burning Windmill at Stege is an unusual fire-painting following a traditional sub-genre of the Dutch Golden Age. Although painted well before Impressionism, Dahl echoes the red of the flames in the field and trees to the left of the windmill, and even in his signature.

Johan Barthold Jongkind, Winter View with Skaters (1864), oil on canvas, dimensions not known, Teylers Museum, Haarlem. Wikimedia Commons.
Johan Barthold Jongkind (1819-1891), Winter View with Skaters (1864), oil on canvas, 43 x 57 cm, Teylers Museum, Haarlem. Wikimedia Commons.

During the winter of 1864, Johan Jongkind returned to the Netherlands, where he painted this Winter View with Skaters, which is more overtly pre-Impressionist.

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Johan Jongkind (1819–1891), Windmill at Antwerp (1866), watercolour over black chalk, 23 x 35.1 cm, Metropolitan Museum of Art, New York, NY. Wikimedia Commons.

Jongkind’s watercolour sketch of a Windmill at Antwerp of 1866 is even more painterly.

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Claude Monet (1840–1926), The Windmill on the Onbekende Gracht, Amsterdam (1874), oil on canvas, 54 x 64.1 cm, Museum of Fine Arts, Houston, TX. Wikimedia Commons.

Claude Monet’s second visit to the Netherlands in 1874 ensured that The Windmill on the Onbekende Gracht, Amsterdam (1874) became a part of the history of Impressionism. This shows a windmill known as Het Land van Beloften, De Eendracht or De Binnen Tuchthuismolen, which was built in the late seventeenth century, and was moved from there to Utrecht just a couple of years after Monet painted it on the banks of the River Amstel.

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Frits Thaulow (1847–1906), View of Amerikavej in Copenhagen (1881), oil on panel, 107.4 x 152.5 cm, Statens Museum for Kunst (Den Kongelige Malerisamling), Copenhagen, Denmark. Wikimedia Commons.

Frits Thaulow’s painstakingly detailed View of Amerikavej in Copenhagen (1881) shows a windmill in the background, where it’s being used to provide power to the adjacent industrial site.

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Volodymyr Orlovsky (1842–1914), Ukrainian Landscape (1882), media and dimensions not known, Private collection. Wikimedia Commons.

Volodymyr Orlovsky’s Ukrainian Landscape from 1882 shows one of the distinctive windmills on the elevated bank alongside a major river and its more populated floodplain to the right.

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Claude Monet (1840–1926), Tulip Field in Holland (1886), oil on canvas, 66 x 82 cm, Musée d’Orsay, Paris. Wikimedia Commons.

It may not have been Monet who first made the visual association between Dutch windmills and fields of tulips in flower, but his 1886 painting of Tulip Field in Holland must be its best-known depiction.

Vincent van Gogh, Le Moulin de la Gallette (1887), oil on canvas, 46 x 38 cm, The Carnegie Museum of Art, Pittsburgh. WikiArt.
Vincent van Gogh (1853–1890), Le Moulin de la Gallette (1887), oil on canvas, 46 x 38 cm, The Carnegie Museum of Art, Pittsburgh. WikiArt.

When Vincent van Gogh moved to Paris in 1886, he stayed with his brother Theo in Montmartre. He painted a series of marvellous views of the remaining windmills there, including the most famous of them all, Le Moulin de la Galette (1887), in whose gardens Renoir had painted his Bal du moulin de la Galette a decade earlier.

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Paul Signac (1863-1935), Rotterdam. The Windmill. The Canal. Morning (Cachin 439) (1906), oil on canvas, 46 x 54.5 cm, Kröller-Müller Museum, Otterlo, The Netherlands. Wikimedia Commons.

Paul Signac’s Rotterdam. The Windmill. The Canal. Morning (1906) is a Divisionist view of a windmill in the centre of this major port.

It was a Dutch painter who took windmills from Impressionism to the modernist styles of the twentieth century: Piet Mondrian.

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Piet Mondrian (1872–1944), Oostzijdse Mill on the River Gein by Moonlight (c 1903), oil on canvas, 63 x 75.4 cm, Rijksmuseum Amsterdam, Amsterdam, The Netherlands. Wikimedia Commons.

Piet Mondrian’s gentle nocturne of Oostzijdse Mill on the River Gein by Moonlight from about 1903 is one of several views of windmills that he painted in Impressionist and post-Impressionist style.

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Piet Mondrian (1872–1944), Mill in Sunlight (c 1908), oil on canvas, 114 x 87 cm, Kunstmuseum Den Haag, The Hague, The Netherlands. Wikimedia Commons.

When he started experimenting with vibrant colour and patterned brushstrokes in about 1908, this painting of a Mill in Sunlight marks his point of departure.

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Piet Mondrian (1872–1944), The Red Mill (1911), oil on canvas, 150 x 86 cm, Kunstmuseum Den Haag, The Hague, The Netherlands. Wikimedia Commons.

The Red Mill (1911) continues Mondrian’s move towards areas of flat colour. That year he left the windmills of Amsterdam and moved to Paris. To mark his move into the avant garde of that city, he dropped the second ‘a’ from his surname, going from Mondriaan to Mondrian. He became increasingly influenced by Georges Bracque and the Cubist works of Pablo Picasso, and the purely abstract paintings for which he remains well-known today.

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Serhii Svitoslavskyi (1857–1931), Ukrainian Landscape with Windmills (c 1911), media and dimensions not known, Sochi Art Museum, Sochi, Russia. Wikimedia Commons.

Serhii Svitoslavskyi’s Ukrainian Landscape with Windmills, probably from about 1911, shows a small cluster of windmills with grazing livestock.

By the end of the First World War, milling grain had become more centralised, and the hundreds of thousands of small windmills across northern Europe lost their business. A few have been preserved, and some are still used for specialist products such as stoneground flour. But the unmistakable sight of a windmill on the skyline had been lost from much of the land.

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Eric Ravilious (1903–1942), Windmill (1934), graphite and watercolour on paper, 44.5 x 55.5 cm, Private collection. Wikimedia Commons.

During the 1930s, the Raviliouses started spending time in Sussex, where they became close friends with Peggy Angus, whose house The Furlongs at Beddingham, East Sussex, became a second home. Eric Ravilious became particularly fond of painting the chalk downs there, as in his Windmill (1934). This isn’t a windmill in the traditional sense, but a smaller wind-driven pump to extract water from the chalk, mainly for irrigation.

A green weekend: Viridian

By: hoakley
17 August 2025 at 19:30

The element chromium gains its name from the rich colours seen in many of its salts and compounds. One of them, chromium oxide, was discovered in about 1798 by Louis-Nicolas Vauquelin, who immediately recognised its future use as a pigment, because of its “fine emerald colour”. But painters were still enamoured with more toxic greens, and straight chromium oxide doesn’t look particularly brilliant, being a rather dull yellow-green. Its introduction into paintings probably didn’t start until around 1840, when landscape painting outdoors was becoming all the rage.

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Moritz von Schwind (1804–1871), Mermaids Watering a Stag (c 1846), oil on canvas, 69 × 40 cm, Sammlung Schack, Bayerische Staatsgemäldesammlungen, Munich, Germany. Wikimedia Commons.

Some of the earliest paintings known to use chromium oxide are those of Moritz von Schwind, of which the first example that I can show is his Mermaids Watering a Stag from about 1846. He seems to have used the pigment quite extensively here in foliage, although probably in combination with other pigments.

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Moritz von Schwind (1804–1871), King Krokus and the Wood Nymph (c 1855), oil on canvas, 78.7 x 45.5 cm, Bayerische Staatsgemäldesammlungen, Munich, Germany. Wikimedia Commons.

Von Schwind’s King Krokus and the Wood Nymph from about 1855 is a clearer image, where he probably used chromium oxide in combination for most of his greens.

As these works were being painted, an improved version of chromium oxide was being developed: hydrated chromium oxide, which became known as viridian during the 1860s. This first became available at a reasonable price after Guignet started to make it in quantity in 1859, so has also been known as Guignet’s green. It’s sometimes termed émeraude or emerald, which only serves to confuse viridian with copper acetoarsenate, more widely known as emerald green.

Viridian came into use during the 1860s, and has proved far more popular than chromium oxide. Both pigments are reliably lightfast, opaque, and have good covering power, but viridian is the more intense, and doesn’t appear dull like plain chromium oxide.

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Anselm Feuerbach (1829–1880), Paolo and Francesca (1864), oil on canvas, 137 × 99.5 cm, Sammlung Schack, Bayerische Staatsgemäldesammlungen, Munich, Germany. Wikimedia Commons.

Anselm Feuerbach’s painting of Paolo and Francesca from 1864 is one of the earlier works found to contain viridian among its many rich greens.

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Édouard Manet (1832–1883), The Balcony (1868-69), oil on canvas, 170 × 124.5 cm, Musée d’Orsay, Paris. Wikimedia Commons.

The best example showing off the colour of viridian is perhaps Édouard Manet’s The Balcony (1868-69), where he appears to have used the pigment throughout the blinds and railings, most probably mixed with lead white, and unmixed for the woman’s parasol.

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Arnold Böcklin (1827–1901), Triton and Nereid (1874), tempera on canvas, 105.3 × 194 cm, Sammlung Schack, Bayerische Staatsgemäldesammlungen, Munich, Germany. Wikimedia Commons.

Arnold Böcklin’s Triton and Nereid from 1874 is unusual in several respects. It’s reported as being painted in tempera rather than oils, but its deep lustrous greens were developed using a base of predominantly viridian, over which Böcklin applied a copper resinate glaze.

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Pierre-Auguste Renoir (1841-1919), La Yole (The Skiff) (1875), oil on canvas, 71 x 92 cm, The National Gallery (Bought, 1982), London. Courtesy of and © The National Gallery, London.

Pierre-Auguste Renoir’s La Yole (The Skiff) of 1875 uses viridian as the main colour for the reeds in the left foreground.

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Claude Monet (1840–1926), Arrival of the Normandy Train, Gare Saint-Lazare (1877), oil on canvas, 59.6 x 80.2 cm, Art Institute of Chicago, Chicago, IL. Wikimedia Commons.

Analysis of Claude Monet’s series of paintings of the Gare Saint-Lazare in 1877 has revealed extensive use of viridian in mixtures, including the green shadows in the roof. In Arrival of the Normandy Train, Gare Saint-Lazare (1877), the pigment is apparent (and confirmed) throughout the green foreground of the platform, an optical effect resulting from light passing through the glass roof of the station.

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Pierre-Auguste Renoir (1841–1919), Chrysanthemums (1881-82), oil on canvas, 54.7 × 65.9 cm, Art Institute of Chicago, Chicago, IL. Image by Rlbberlin, via Wikimedia Commons.

Renoir used viridian together with malachite green and other pigments for the greens in his Chrysanthemums (1881-82).

Georges Seurat, Un dimanche après-midi à l'Île de la Grande Jatte (A Sunday Afternoon on the Island of La Grande Jatte) (1884-6), oil on canvas, 207.5 × 308.1 cm, Art Institute of Chicago, Chicago, IL. Wikimedia Commons.
Georges Seurat (1859-91), Un dimanche après-midi à l’Île de la Grande Jatte (A Sunday Afternoon on the Island of La Grande Jatte) (1884-6), oil on canvas, 207.5 × 308.1 cm, Art Institute of Chicago, Chicago, IL. Wikimedia Commons.

If you care to spend some time examining the myriads of tiny dots in Georges Seurat’s monumental Divisionist painting of A Sunday Afternoon on the Island of La Grande Jatte (1884-86), I’m assured that you’ll find many of those forming its vegetation contain viridian.

Viridian remained popular among the post-Impressionists, from whom I have two well-known paintings as examples.

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Vincent van Gogh (1853-1890), A Wheatfield, with Cypresses (1889), oil on canvas, 72.1 × 90.9 cm, The National Gallery (Bought, Courtauld Fund, 1923), London. Courtesy of and © The National Gallery, London.

Vincent van Gogh included viridian in the pigments used in the range of greens in his A Wheatfield, with Cypresses (1889), which is more unusual for his use of ultramarine blue mixed to form green.

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Paul Cézanne (1839-1906), Hillside in Provence (1890-92), oil on canvas, 63.5 x 79.4 cm, The National Gallery (Bought, Courtauld Fund, 1926), London. Courtesy of and © The National Gallery, London.

Paul Cézanne is known to have had a strong preference for viridian as one of the key colours in his palette. However, in his Hillside in Provence (1890-92), it is emerald green that is the more prominent, and the major part of the painting’s more brilliant greens, even into its pale turquoise sky. Some green passages, such as the patch of yellow-green grass at the edge of the path in the foreground, at the right edge of the canvas, have been built with a base of lead white and viridian, over which he has applied a yellow lake glaze.

Chromium oxide and viridian remain widely available today; although the former is not popular or widely used, viridian remains a mainstay green widely recommended for its colour and other properties. Being virtually insoluble, chromium oxide and viridian pose minimal risks of toxicity to the artist. However, there is growing concern over their environmental effects, and great care is needed when handling waste paint containing either pigment.

Reference

Richard Newman (1997) Artists’ Pigments, vol 3, ed Elisabeth West FitzHugh, Archetype. ISBN 978 1 904982 76 0.

The first modern pigment: Prussian blue

By: hoakley
3 August 2025 at 19:30

Until the advent of chemistry in the eighteenth century, early in the Age of Enlightenment, the vast majority of pigments occurred in nature, even if the minerals or plant matter from which they were derived had to be specially processed. The first truly synthetic pigment was so ancient that it had been forgotten completely by the Middle Ages: Egyptian blue was originally made before about 3000 BCE by heating together powdered rocks and sand, but that was an exception. It wasn’t until the early years of the eighteenth century that a hydrated iron hexacyanoferrate complex soon known as Prussian blue was synthesized.

No one knows who first made Prussian blue, nor exactly when it was first synthesized. It seems to have appeared initially around 1704, and its origins have been attributed variously to Diesbach in Berlin, or Mak in Leipzig. For once its name is appropriate, as it was a product of the Prussian Empire. Its potential as a colourant was recognised by 1710 when it went on sale in Berlin, and by about 1724 it was being manufactured across Europe.

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Adriaen van der Werff (1659-1722) and Henrik van Limborch (1681-1759), Jacob Blessing the Sons of Joseph (before 1722-28), oil on panel, 61.1 x 47.5 cm, Allen Memorial Art Museum (Mrs. F. F. Prentiss Fund, 1963), Oberlin, OH. . Courtesy of the Allen Memorial Art Museum.

Among the earliest surviving oil paintings to use Prussian Blue is that by Adriaen van der Werff and Henrik van Limborch, of Jacob Blessing the Sons of Joseph. This was started by van der Werff before he died in 1722, and the paint containing Prussian blue pigment is thought to have been applied by him to the curtain at the upper left. After van der Werff’s death, his pupil Henrik van Limborch finished the painting between 1727-28.

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Antoine Watteau (1684–1721), The Italian Comedians (c 1720), oil on canvas, 63.8 x 76.2 cm, National Gallery of Art, Washington, DC. Wikimedia Commons.

Another early example of the proven use of Prussian blue is Antoine Watteau’s The Italian Comedians from about 1720.

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Canaletto (1697–1768) (attr), Grand Canal from Palazzo Balbi toward the Rialto (1720-23), oil on canvas, 144 x 207 cm, Ca’ Rezzonico, Venice, Italy. Wikimedia Commons.

Canaletto is one of the first Masters to have used the new pigment extensively. Grand Canal from Palazzo Balbi toward the Rialto from 1720-23 has been attributed to him as one of his earliest surviving works, and its blues have been found to contain Prussian blue.

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Canaletto (1697–1768), Rio dei Mendicanti (1723-24), oil on canvas, 143 x 200 cm, Ca’ Rezzonico, Venice, Italy. Wikimedia Commons.

Canaletto was quick to adopt the pigment for use in almost all his paintings, including this view of the Rio dei Mendicanti from 1723-24, above, and his famous The Stonemason’s Yard (c 1725), below.

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Canaletto (Giovanni Antonio Canal) (1697–1768), Campo S. Vidal and Santa Maria della Carità (‘The Stonemason’s Yard’) (c 1725), oil on canvas, 123.8 x 162.9 cm, The National Gallery (Sir George Beaumont Gift, 1823), London. Image courtesy of and © The National Gallery, London.

As experience was gained in using this pigment, it became controversial. Some artists were confident that its colour was stable and didn’t change or fade, but others experienced problems as bad as or even worse than those of the notoriously fugitive indigo blue, which it had generally replaced. It has gradually become understood that adverse results of lightfastness testing (and experience in paintings) have depended on the mixture of Prussian blue with other colours, particularly with white paint, and the presence of impurities in the pigment.

By the middle of the eighteenth century, Prussian blue was widely used with a range of binding media, with the notable exception of fresco and other alkaline media with which it proved incompatible.

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William Hogarth (1697–1764), Marriage A-la-Mode: 2, The Tête à Tête (c 1743), oil on canvas, 69.9 × 90.8 cm, The National Gallery, London. Courtesy of The National Gallery London, inventory NG114.

William Hogarth’s paintings in his Marriage A-la-Mode series have been found to contain both smalt and Prussian blues. In The Tête à Tête (c 1743), smalt has been found in the ornate carpet, and I suspect that the ornamental pillars behind the woman rely on Prussian blue, at least in part. Hogarth trained as Prussian blue came to the ascendant, and wouldn’t have painted much before it had become widely available.

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Jean-Baptiste Perronneau (1715/16-1783), A Girl with a Kitten (c 1743), pastel on paper, 59.1 x 49.8 cm, The National Gallery (Presented by Sir Joseph Duveen, 1921), London. Image courtesy of and © The National Gallery, London.

Jean-Baptiste Perronneau’s A Girl with a Kitten from about 1743 is a fine example of the use of Prussian blue in pastels: the girl’s blue dress and the background have both been found to contain the pigment.

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William Blake (1757-1827), Lucia Carrying Dante in his Sleep (from Dante’s “Divine Comedy”) (1824-27), watercolour, black ink, graphite, and black chalk on off-white antique laid paper, 37.2 x 52.2 cm, Harvard Art Museums/Fogg Museum (Bequest of Grenville L. Winthrop), Cambridge, MA. Courtesy of Harvard Art Museums/Fogg Museum.

Prussian blue also became popular in water-based media. William Blake’s Lucia Carrying Dante in his Sleep, from his series depicting Dante’s Divine Comedy painted in watercolour between 1824-27, is a good example. In this and several other of his paintings, Blake used the pigment on its own and mixed with gamboge yellow in what was known as Prussian green.

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James Abbott McNeill Whistler (1834–1903), The Princess from the Land of Porcelain (1863-65), oil on canvas, dimensions not known, Freer Gallery of Art, Smithsonian Institution, Washington, DC. Wikimedia Commons.

Prussian blue pigment has been found in the blue passages in Whistler’s The Princess from the Land of Porcelain (1863-65), from his Peacock Room, shown above and in the detail below.

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James Abbott McNeill Whistler (1834–1903), The Princess from the Land of Porcelain (detail) (1863-65), oil on canvas, dimensions not known, Freer Gallery of Art, Smithsonian Institution, Washington, DC. Wikimedia Commons.

The use of different blue pigments varied markedly among the French Impressionists and their successors. Paul Cézanne and Georges Seurat appear to have used Prussian blue seldom if at all, but it’s well known in the work of Edgar Degas, Claude Monet and Vincent van Gogh.

Claude Monet, Bathers at la Grenouillère (1869), oil on canvas, 73 x 92 cm, The National Gallery, London. WikiArt.
Claude Monet (1840-1926), Bathers at la Grenouillère (1869), oil on canvas, 73 x 92 cm, The National Gallery, London. WikiArt.

Although Monet’s Bathers at la Grenouillère (1869) contains cobalt blue in the brighter mid-blues of the water surface and details in the boats, darker blues towards the left, and in the clothing of some of the figures and their reflections, are almost certainly Prussian blue.

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Vincent van Gogh (1853-1890), La Mousmé (1888), oil on canvas, 73.3 x 60.3 cm, The National Gallery of Art (Chester Dale Collection), Washington, DC. Courtesy of The National Gallery of Art.

Vincent van Gogh’s portrait of La Mousmé from 1888 illustrates some of the difficulties of identifying pigment use. Its unusual title is derived from the Japanese word musume, meaning girl; at the time the French word was understood to mean an ‘easy’ girl.

Infra-red images demonstrate van Gogh’s use of at least two different blues, one of which has been identified as Prussian blue. The two (or more) blue pigments aren’t distributed evenly: on the girl’s jacket, the three blue stripes to the left of the row of buttons contain the most Prussian blue, while the three under her right armpit, which look darker, contain little or no Prussian blue. Van Gogh also mixed yellow with Prussian blue to form the green of the flowers she holds in her hand.

Prussian blue remained a popular pigment in oil and watercolour paints well into the twentieth century, and is still offered in commercial ranges. For many artists, though, it has been replaced by much more recent synthetic blue pigments, such as phthalocyanine (‘phthalo’) blue, introduced around 1970, and is seldom used in Prussian green.

Reference

Barbara H Berrie (1997) Artists’ Pigments, vol 3, ed Elisabeth West Fitzhugh, Archetype. ISBN 978 1 904982 76 0.

Blue from over the sea: ultramarine

By: hoakley
2 August 2025 at 19:30

Blue pigments used in painting include some of the oldest used by man, and others that led the change to modern synthetic pigments driven by the arrival of chemistry in the eighteenth century. This weekend I look at two examples, today the queen of pigments, ultramarine, and tomorrow the first synthetic chemical, Prussian blue.

Originally made by crushing and grinding the semi-precious stone lapis lazuli, the cost of ultramarine has exceeded that of gold. Seen in paintings, it produces a rich slightly reddish blue which stands the test of time, as distinctive and effective today as when it was first used. And its use has a history of unmasking fakes and forgeries.

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Artist not known, wall paintings by the Buddahs of Bamiyan, Afghanistan, c 507-554 CE. Image by Carl Montgomery, via Wikimedia Commons.

The sole source of lapis lazuli in Europe and the West were quarries in Badakshan, described by Marco Polo and now in Afghanistan. It appears that wall paintings made around 507-554 CE adjacent to the great Buddahs of Bamiyan were the first to have used the mineral as a pigment. It was then used in early Persian miniatures, and in early Chinese and Indian paintings too. Tragically, these wall paintings in Bamiyan, Afghanistan, were damaged by the Taliban in 2001 when the two statues were destroyed, and their restoration has made little progress since.

The powdered pigment had made its way, first along the Silk Road, then by sea, to traders in Venice by about 1300. By the Renaissance, it was established as one of the most important and precious of all the pigments used in European art.

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Duccio (fl 1278-1319), The Healing of the Man born Blind (Maestà Predella Panels) (1307/8-11), egg tempera on wood, 45.1 x 46.7 cm, The National Gallery (Bought, 1883), London. Courtesy of and © The National Gallery, London.

Because of its beauty and high cost, ultramarine blue was used for the robes of Jesus Christ and the Virgin Mary. Duccio’s panels from the Maestà Predella, including this of The Healing of the Man born Blind, show this tradition in its earliest years, around 1307-11. As a pigment, it proved practical in egg tempera as here, and in oils, watercolour, and fresco.

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Jan van Eyck (c 1390–1441) and Hubert van Eyck (c 1366-1426), The Ghent Altarpiece (c 1432), oil on panel, open overall 350 x 461 cm, Saint Bavo Cathedral, Gent, Belgium. Wikimedia Commons.

Ultramarine blue has been found in the van Eyck brothers’ Ghent Altarpiece from about 1432 (above), and particularly in its most famous panel, The Mystic Lamb, below.

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Jan van Eyck (c 1390–1441) and Hubert van Eyck (c 1366-1426), The Mystic Lamb, part of the Ghent Altarpiece (detail) (c 1432), oil on panel, open overall 350 x 461 cm, Saint Bavo Cathedral, Gent, Belgium. Wikimedia Commons.
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Sandro Botticelli (c 1445-1510) and Filippino Lippi (c 1457-1504), Adoration of the Kings (c 1470), tempera on wood, 50.2 x 135.9 cm, The National Gallery (Bought, 1857), London.

Sandro Botticelli’s early tempera on panel painting Adoration of the Kings from about 1470, apparently made with Filippino Lippi, shows two different blue colours and purple. He painted the purple with an opaque underpainting of lead white tinted with a red lake derived from madder, to create pink. That was then glazed with quite coarse particles of ultramarine blue, so the pigment was thinly dispersed.

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Peter Paul Rubens (1577–1640), Descent from the Cross (centre panel of triptych) (1612-14), oil on panel, 421 x 311 cm, Onze-Lieve-Vrouwekathedraal, Antwerp, Belgium. Image by Alvesgaspar, via Wikimedia Commons.

Peter Paul Rubens used ultramarine blue widely in his magnificent triptych now in Antwerp Cathedral. In its centre panel, Descent from the Cross (1612-14), it has been found combined with indigo and other pigments.

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Anthony van Dyck (1599-1641), Charity (1627-8), oil on oak, 148.2 x 107.5 cm, The National Gallery (Bought, 1984), London. Courtesy of and © The National Gallery, London.

In van Dyck’s Charity from 1627-8, its most obvious use is in the blue cape, where ultramarine blue was painted over indigo, applied as both a tint and as a glaze over the top.

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Sassoferrato (1609-1685), The Virgin in Prayer (1640-50), oil on canvas, 73 x 57.7 cm, The National Gallery (Bequeathed by Richard Simmons, 1846), London. Courtesy of and © The National Gallery, London.

Visit any of the larger galleries with substantial collections of paintings made before 1700, and you will see works with drapery that I can only describe as arresting in the brilliance of their ultramarine blue. One stunning example in the National Gallery in London is Sassoferrato’s The Virgin in Prayer from 1640-50. The Virgin’s cloak looks as if it was painted only yesterday, and that colour makes you stop in your tracks and draws you into the painting, like no other pigment can.

Given its importance, and limited supply, considerable effort was devoted to ensuring that natural ultramarine blue was of the highest quality, and alternative sources were sought. Deposits in the Chilean Andes, and near Lake Baikal in Siberia, weren’t developed until the nineteenth century, and attempts to make synthetic ultramarine proved unsuccessful until 1828, when Jean Baptiste Guimet was awarded a prize of six thousand francs for his discovery. Almost simultaneously, C G Gmelin of Tübingen discovered a slightly different method.

Commercial production had started by 1830, and it became known as French ultramarine, to distinguish it from the natural pigment. Although almost identical in colour and performance, there are significant differences between natural and synthetic ultramarine when tested in the laboratory. This has enabled the examination of paintings to determine the source of their pigment, and has brought some surprises. These most often relate to later overpainting during restoration. For example, two areas of much later painting have been discovered in the van Eycks’ Ghent Altarpiece.

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Édouard Manet (1832-1883), Corner of a Café-Concert (1878-80), oil on canvas, 97.1 x 77.5 cm, The National Gallery (Bought, Courtauld Fund, 1924), London. Courtesy of and © The National Gallery, London.

Examination of Édouard Manet’s Corner of a Café-Concert, from 1878-80, has shown that he used synthetic ultramarine in its blue passages, for example.

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Pierre-Auguste Renoir (1841-1919), The Umbrellas (c 1881-86), oil on canvas, 180.3 x 114.9 cm, The National Gallery (Sir Hugh Lane Bequest, 1917), London. Courtesy of and © The National Gallery, London.

Pierre-Auguste Renoir’s The Umbrellas, from about 1881-86, uses synthetic ultramarine in a methodical fashion. The first stage in its painting used only cobalt blue, but in its second stage synthetic ultramarine was applied extensively.

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Vincent van Gogh (1853-1890), A Wheatfield, with Cypresses (1889), oil on canvas, 72.1 × 90.9 cm, The National Gallery (Bought, Courtauld Fund, 1923), London. Courtesy of and © The National Gallery, London.

Vincent van Gogh’s A Wheatfield, with Cypresses (1889) contains synthetic ultramarine in its deepest blues, and in some areas of green, although it’s unusual to find ultramarine mixed to form green. Before synthetic pigment became available, this would have been far too expensive a way of making any significant amount of green, but once much cheaper pigment came onto the market, that became more feasible, if still unusual.

The ability to distinguish synthetic ultramarine, which didn’t exist before about 1828, and the natural pigment has proved important in detecting some forgeries. Only the most ignorant would attempt to pass off a painting made with synthetic ultramarine as being very old, but a few fakes fell at that hurdle.

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Han van Meegeren (1889–1947), The Men at Emmaus (1937), oil on canvas, dimensions not known, Museum Boijmans Van Beuningen, Rotterdam, The Netherlands. Wikimedia Commons.

Han van Meegeren was far too knowledgeable and cunning to be caught so easily. He used natural ultramarine, for example when he sold The Men at Emmaus (1937) to the Museum Boijmans Van Beuningen as a Vermeer. What no one knew at the time was that his ultramarine looked genuine, but had been contaminated with a small amount of cobalt blue, which wasn’t discovered until 1803-04, and was first used as a pigment in 1806.

In 1960, the modern artist Yves Klein worked with the paint supplier Edouard Adam to ‘invent’ a paint he termed International Klein Blue (IKB). Although its formulation is a secret, it’s almost entirely synthetic ultramarine blue pigment in a polyvinyl acetate binder.

Like all the best queens, ultramarine blue has an unnerving habit of revealing the truth.

Reference

Joyce Plesters (1993) Artists’ Pigments, vol 2, ed Ashok Roy, Archetype. ISBN 978 1 904982 75 3.

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